Mrs. Peoples-Pierce received a Bachelor of Science degree in Strategic Communications with an emphasis in Social Media Management, as well as a minor in History from Arkansas State University in the winter of 2018. She then earned a J.D. from The University of Memphis, Cecil C. Humphreys School of Law in 2022.

During her time at law school, Mrs. Peoples-Pierce interned with Just City of Memphis where she was able to display her interest in the criminal legal system, clerked for a local Memphis family law firm specializing in divorce and mediation, and participated as a student attorney at the Medical-Legal Partnership Clinic. She also earned the CALI award for the Medical-Legal Partnership Clinic while in law school. Mrs. Peoples-Pierce was a member of the Health Law Society, Public Action Law Society, Street Law, and Association for Women Attorneys. Additionally, Mrs. Peoples-Pierce clerked in Crittenden County at a firm working on probate matters as well as personal injury cases.

In her spare time, Mrs. Peoples-Pierce enjoys going to the movie theater, reading, cardio, learning information about cars, spending time with her husband and little sister, and caring for her pets.